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KAIST Achieves 3-fold Increase in Hydrogen Production Using “High-Entropy” Design—More Mixing, More Strength
<(From Left) Professor Kang Taek Lee, Ph.D candidate Seeun Oh, Researcher Incheol Jeong, Dr. Dongyeon Kim, Ph.D candidate Hyeonggeun Kim>
While mixing materials typically leads to instability, there exists a phenomenon known as “high entropy,” where increasing compositional complexity can actually enhance stability. KAIST researchers leveraged this principle to enable faster proton transport and more efficient reactions within electrochemical cells, developing a technology that significantly improves hydrogen production efficiency. This breakthrough is expected to reduce hydrogen costs and accelerate the transition to clean energy.
KAIST (President Kwang Hyung Lee) announced on the 5th of April that a research team led by Professor Kang Taek Lee from the Department of Mechanical Engineering has developed a novel oxygen electrode material that dramatically improves reaction kinetics and power performance through entropy-maximized design. The oxygen electrode is a key component in electrochemical cells where oxygen evolution occurs during hydrogen production.
Green hydrogen—produced from water without carbon emissions—is considered a cornerstone of future clean energy systems. In particular, protonic ceramic electrochemical cells (PCECs), which generate hydrogen by splitting water using electrical energy while protons migrate through the cell, have attracted attention for their high efficiency. However, their performance has been limited by slow reaction kinetics at the oxygen electrode.
To address this issue, the research team adopted a high-entropy strategy, introducing multiple metal elements simultaneously to increase configurational disorder. Although mixing many elements typically destabilizes structures, under certain compositions, maximizing entropy can instead stabilize a single-phase structure.
<Structural and chemical characterization of PBSCF and PLNNCBSCF. XRD patterns of a) the synthesized PBSCF and PLNNCBSCF and b) enlarged view of the XRD patterns from 31.5 to 33.5°. c) Rietveld refinement results of the XRD profile for PLNNCBSCF, with the inset showing the idealized structure. d) HR-TEM image of PLNNCBSCF with the inset showing lattice fringes. e) Corresponding EDS mappings of the PLNNCBSCF elements. XPS of F) survey peak, G) Pr 3d, and H) O 1s spectra for PBSCF and PLNNCBSCF>
Based on this concept, the researchers designed a high-entropy double perovskite oxygen electrode by incorporating seven different metal elements (Pr, La, Na, Nd, Ca, Ba, Sr) into the A-site of the electrode structure. This material combines a perovskite crystal framework with a double perovskite structure, further enhanced by high-entropy design.
The presence of multiple mixed metal elements improves charge transport and oxygen-related reactions within the electrode, resulting in significantly faster electrochemical reactions for both electricity generation and hydrogen production.
Notably, density functional theory (DFT) calculations revealed that the energy required to form oxygen vacancies—active sites where reactions occur—was reduced by more than 60% compared to conventional materials. This indicates that reactive sites can form more easily and in greater abundance.
Additionally, time-of-flight secondary ion mass spectrometry (TOF-SIMS) analysis showed that proton transport speed increased by more than sevenfold, demonstrating that hydrogen generation processes proceed much more efficiently within the electrode.
The performance improvements were substantial. Cells incorporating the new electrode achieved a power density of 1.77 W cm⁻² at 650°C, approximately 2.6 times higher than conventional systems. Hydrogen production performance also improved by approximately threefold (4.42 A cm⁻²) under the same conditions.
Moreover, in long-term testing under steam conditions for 500 hours, performance degradation was only 0.76%, confirming excellent durability and stability over extended operation.
Professor Kang Taek Lee stated, “This study demonstrates that the thermodynamic concept of entropy can be used to control electrode reactivity,” adding, “It has the potential to significantly enhance green hydrogen production efficiency and accelerate the commercialization of the hydrogen economy.”
This study was co-led by Seeun Oh of the Department of Mechanical Engineering at KAIST and Incheol Jeong of the Korea Institute of Geoscience and Mineral Resources. The findings were published on December 16, 2025, in the international journal Advanced Energy Materials (IF: 26.0) and were selected as a front cover article, highlighting their scientific impact.
※ Paper title: “Unveiling Entropy-Driven Performance Enhancement in Double Perovskite Oxygen Electrodes for Protonic Ceramic Electrochemical Cells,” DOI: https://doi.org/10.1002/aenm.202503176※ Authors: Seeun Oh (KAIST, first author), Incheol Jeong (Korea Institute of Geoscience and Mineral Resources, first author), Dongyeon Kim (second author), Hyeonggeun Kim (second author), Kang Taek Lee (corresponding author)
This research was supported by the Mid-Career Researcher Program and the Global Basic Research Laboratory Program funded by the Ministry of Science and ICT (MSIT), Korea.
2026.04.06 View 339 -
KAIST, Production Temperature ↓ by 500°C, Power Output ↑ 2x… Next-Generation Ceramic Electrochemical Cell Reborn
<(Top row, from left) Professor Kang Taek Lee, Ph.D candidate Yejin Kang, Dr. Dongyeon Kim, (Bottom row, from left) M.S candidate Mincheol Lee, Ph.D candidate Seeun Oh, Ph.D candidate Seungsoo Jang, Ph.D candidate Hyeonggeun Kim>
As power demand surges in the AI era, the “protonic ceramic electrochemical cell (PCEC),” which can simultaneously produce electricity and hydrogen, is gaining attention as a next-generation energy technology. However, this cell has faced the technical limitation of requiring an ultra-high production temperature of 1,500°C. A KAIST research team has succeeded in establishing a new manufacturing process that lowers this limit by more than 500°C for the first time in the world.
KAIST (President Kwang Hyung Lee) announced on the 4th of December that Professor Kang Taek Lee’s research team in the Department of Mechanical Engineering developed a new process that enables the fabrication of high-performance protonic ceramic electrochemical cells at temperatures more than 500°C lower than before, using “microwave + vapor control technology” that leverages microwave heating principles and the diffusion environment of chemical vapor generated from specific chemical components.
The electrolyte—the key material of protonic ceramic electrochemical cells—contains barium (Ba), and barium easily evaporates at temperatures above 1,500°C, which has been the main cause of performance degradation. Therefore, the ability to harden the ceramic electrolyte at a lower temperature has been the core issue that determines cell performance.
As power demand surges in the AI era, the “protonic ceramic electrochemical cell (PCEC),” which can simultaneously produce electricity and hydrogen, is gaining attention as a next-generation energy technology. However, this cell has faced the technical limitation of requiring an ultra-high production temperature of 1,500°C. A KAIST research team has succeeded in establishing a new manufacturing process that lowers this limit by more than 500°C for the first time in the world.
KAIST (President Kwang Hyung Lee) announced on the 4th of December that Professor Kang Taek Lee’s research team in the Department of Mechanical Engineering developed a new process that enables the fabrication of high-performance protonic ceramic electrochemical cells at temperatures more than 500°C lower than before, using “microwave + vapor control technology” that leverages microwave heating principles and the diffusion environment of chemical vapor generated from specific chemical components.
The electrolyte—the key material of protonic ceramic electrochemical cells—contains barium (Ba), and barium easily evaporates at temperatures above 1,500°C, which has been the main cause of performance degradation. Therefore, the ability to harden the ceramic electrolyte at a lower temperature has been the core issue that determines cell performance.
To solve this, the research team devised a new heat-treatment method called “vapor-phase diffusion.” This technique places a special auxiliary material (a vapor source) next to the cell and irradiates it with microwaves to quickly diffuse vapor. When the temperature reaches approximately 800°C, the vapor released from the auxiliary material moves toward the electrolyte and tightly bonds the ceramic particles. Thanks to this technology, a process that previously required 1,500°C can now be completed at just 980°C. In other words, a world-first ceramic electrochemical cell fabrication technology has been created that produces high-performance electricity at a “low temperature” without damaging the electrolyte.
A cell fabricated with this process produced 2 W of power stably from a 1 cm² cell (roughly the size of a fingernail) at 600°C and generated 205 mL of hydrogen per hour at 600°C (about the volume of a small paper cup, among the highest in the industry). It also maintained stability without performance degradation during 500 hours of continuous operation.
In other words, this technology reduces the production temperature (−500°C), lowers the operating temperature (600°C), doubles performance (2 W/cm²), and extends the lifespan (500-hour stability), achieving world-class performance in ceramic cell technology.
The research team also enhanced the reliability of the technology by using digital twins (virtual simulations) to analyze gas-transport phenomena occurring in the microscopic internal structure of the cell − phenomena that are difficult to observe in actual experiments.
<Figure 1. (a) Schematic of the vapor-diffusion-based process; (b) Surface microstructure of the electrolyte; (c) Internal barium composition ratio of the electrolyte according to processing conditions; (d) Comparison of power-generation performance with previous studies>
< Figure 2. (a) Three-dimensional reconstructed image of the protonic ceramic electrochemical cell fuel electrode according to processing conditions (b) Pore structure (c) Gas-transport simulation results >
Professor Kang Taek Lee emphasized, “This study is the world’s first case of using vapor to lower the heat-treatment temperature by more than 500°C while still producing a high-performance, high-stability cell.” He added, “It is expected to become a key manufacturing technology that addresses the power challenges of the AI era and accelerates the hydrogen society.”
Dongyeon Kim (KAIST PhD) and Yejin Kang (KAIST PhD candidate) participated as co–first authors. The research results were published in Advanced Materials (IF: 26.8), one of the world’s leading journals in energy and materials science, and were selected as the Inside Front Cover article on October 29.
(Paper title: “Sub-1000°C Sintering of Protonic Ceramic Electrochemical Cells via Microwave-Driven Vapor Phase Diffusion,” DOI: https://doi.org/10.1002/adma.202506905)
This research was supported by the MSIT’s Mid-career Researcher Program and the H2 Next Round Program.
2025.12.05 View 2627