WooChul+Jung
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A KAIST Research Team Develops an Ultra-High Performing “Universal Electrode” for Next-Generation Fuel Cells
Fuel cells are devices that generate electricity with high efficiency using hydrogen, a clean energy source, and are expected to play an important part in the upcoming hydrogen society. The recent development of an excellent universal electrode material that is applicable to all next-generation fuel cells and can withstand 700 hours of operation has therefore garnered a great deal of attention.
On August 9, a joint research team led by Prof. WooChul Jung from the KAIST Department of Materials Science and Engineering, Prof. Kang Taek Lee from the KAIST Department of Mechanical Engineering, and Prof. Jun Hyuk Kim from the Department of Chemical Engineering at Hongik University announced the development of an electrode material that is applicable to both oxygen- and proton-conducting solid oxide cells.
Depending on the type of ion conducted by the electrolyte, ceramic fuel cells are categorized into either solid oxide fuel cells (SOFC) or protonic ceramic fuel cells (PCFC). As they can both convert between electricity and hydrogen production, fuel cells can be categorized into a total of four device types. These devices are applicable in hydrogen fuel cell vehicles, hydrogen charging stations, and power generation systems, and are henceforth emerging as core next-generation technologies for a carbon-neutral society.
However, these devices have a chronic problem where the speed of their slowest reaction would decrease with a drop of driving temperature, which greatly reduces device efficiency. Various studies have been conducted to solve this, but most reported that electrode materials have low catalytic activity and their applications are limited to specific devices, which limits them from being used as SOFCs that require reversible power conversion and hydrogen production.
< Figure 1. Schematic diagram of high-performance oxygen ion conductive solid oxide fuel cell (SOFC) and proton conductive ceramic fuel cell (PCFC) operates with the new universal electrodes >
To solve this issue, the research team doped a perovskite oxide material with Ta5+, a high valence ion that did not receive much attention in the field. Through this, the team successfully stabilized what is usually a highly unstable crystal structure, and confirmed that catalytic activity improved by 100 times.
The electrode material developed by the team was applied to all four of the mentioned device types. Furthermore, their efficiencies were greater than any of the devices reported thus far, and showed excellent performance by stably running for much longer (700 hours) compared to existing materials that deteriorated within the first 100 hours of operation.
< Figure 2. (a) Power conversion and hydrogen production performance chart for the protonic ceramic fuel cell (PCFC) with the new universal electrodes (b) and performance comparison with other reported devices >
This research, in which KAIST’s Ph.D. candidates Dongyeon Kim and Sejong Ahn, and Professor Jun Hyuk Kim from Hongik University contributed as co-first authors, was published in the internationally renowned Energy & Environmental Science under the title, "Oxygen-Electrode for Reversible Solid Oxide Electrochemical Cells at Reduced Temperatures".
Prof. WooChul Jung said, “We broke free from the idea that we must develop a completely new material to solve an existing problem, and instead suggested a way to control the crystal structure of a lesser-known material to develop a high-efficiency fuel cell, and that’s what makes these results more significant.”
Prof. Kang Taek Lee added, “Unlike previously reported materials that could only be applied to one device type at a time, our material has the flexibility of being applicable to all four. We therefore look forward to its contribution in the commercialization of eco-friendly energy technology including fuel cells and water-splitting equipment for hydrogen production.”
This research was supported by a National Research Foundation of Korea (NRF) grant funded by the Korean Ministry of Science and ICT.
2023.08.22 View 4284 -
ACS Nano Special Edition Highlights Innovations at KAIST
- The collective intelligence and technological innovation of KAIST was highlighted with case studies including the Post-COVID-19 New Deal R&D Initiative Project. -
KAIST’s innovative academic achievements and R&D efforts for addressing the world’s greatest challenges such as the COVID-19 pandemic were featured in ACS Nano as part of its special virtual issue commemorating the 50th anniversary of KAIST. The issue consisted of 14 review articles contributed by KAIST faculty from five departments, including two from Professor Il-Doo Kim from the Department of Materials Science and Engineering, who serves as an associate editor of the ACS Nano.
ACS Nano, the leading international journal in nanoscience and nanotechnology, published a special virtual issue last month, titled ‘Celebrating 50 Years of KAIST: Collective Intelligence and Innovation for Confronting Contemporary Issues.’
This special virtual issue introduced KAIST’s vision of becoming a ‘global value-creative leading university’ and its progress toward this vision over the last 50 years. The issue explained how KAIST has served as the main hub for advanced scientific research and technological innovation in South Korea since its establishment in 1971, and how its faculty and over 69,000 graduates played a key role in propelling the nation’s rapid industrialization and economic development.
The issue also emphasized the need for KAIST to enhance global cooperation and the exchange of ideas in the years to come, especially during the post-COVID era intertwined with the Fourth Industrial Revolution (4IR). In this regard, the issue cited the first ‘KAIST Emerging Materials e-Symposium (EMS)’, which was held online for five days in September of last year with a global audience of over 10,000 participating live via Zoom and YouTube, as a successful example of what academic collaboration could look like in the post-COVID and 4IR eras.
In addition, the “Science & Technology New Deal Project for COVID-19 Response,” a project conducted by KAIST with support from the Ministry of Science and ICT (MSIT) of South Korea, was also introduced as another excellent case of KAIST’s collective intelligence and technological innovation. The issue highlighted some key achievements from this project for overcoming the pandemic-driven crisis, such as: reusable anti-virus filters, negative-pressure ambulances for integrated patient transport and hospitalization, and movable and expandable negative-pressure ward modules.
“We hold our expectations high for the outstanding achievements and progress KAIST will have made by its centennial,” said Professor Kim on the background of curating the 14 review articles contributed by KAIST faculty from the fields of Materials Science and Engineering (MSE), Chemical and Biomolecular Engineering (CBE), Nuclear and Quantum Engineering (NQE), Electrical Engineering (EE), and Chemistry (Chem).
Review articles discussing emerging materials and their properties covered photonic carbon dots (Professor Chan Beum Park, MSE), single-atom and ensemble catalysts (Professor Hyunjoo Lee, CBE), and metal/metal oxide electrocatalysts (Professor Sung-Yoon Chung, MSE).
Review articles discussing materials processing covered 2D layered materials synthesis based on interlayer engineering (Professor Kibum Kang, MSE), eco-friendly methods for solar cell production (Professor Bumjoon J. Kim, CBE), an ex-solution process for the synthesis of highly stable catalysts (Professor WooChul Jung, MSE), and 3D light-patterning synthesis of ordered nanostructures (Professor Seokwoo Jeon, MSE, and Professor Dongchan Jang, NQE).
Review articles discussing advanced analysis techniques covered operando materials analyses (Professor Jeong Yeong Park, Chem), graphene liquid cell transmission electron microscopy (Professor Jong Min Yuk, MSE), and multiscale modeling and visualization of materials systems (Professor Seungbum Hong, MSE).
Review articles discussing practical state-of-the-art devices covered chemiresistive hydrogen sensors (Professor Il-Doo Kim, MSE), patient-friendly diagnostics and implantable treatment devices (Professor Steve Park, MSE), triboelectric nanogenerators (Professor Yang-Kyu Choi, EE), and next-generation lithium-air batteries (Professor Hye Ryung Byon, Chem, and Professor Il-Doo Kim, MSE).
In addition to Professor Il-Doo Kim, post-doctoral researcher Dr. Jaewan Ahn from the KAIST Applied Science Research Institute, Dean of the College of Engineering at KAIST Professor Choongsik Bae, and ACS Nano Editor-in-Chief Professor Paul S. Weiss from the University of California, Los Angeles also contributed to the publication of this ACS Nano special virtual issue.
The issue can be viewed and downloaded from the ACS Nano website at https://doi.org/10.1021/acsnano.1c01101.
Image credit: KAIST
Image usage restrictions: News organizations may use or redistribute this image,with proper attribution, as part of news coverage of this paper only.
Publication:
Ahn, J., et al. (2021) Celebrating 50 Years of KAIST: Collective Intelligence and Innovation for Confronting Contemporary Issues. ACS Nano 15(3): 1895-1907. Available online at https://doi.org/10.1021/acsnano.1c01101
Profile:
Il-Doo Kim, Ph.D
Chair Professor
idkim@kaist.ac.kr
http://advnano.kaist.ac.kr
Advanced Nanomaterials and Energy Lab.
Department of Materials Science and Engineering
Membrane Innovation Center for Anti-Virus and Air-Quality Control
https://kaist.ac.kr/
Korea Advanced Institute of Science and Technology (KAIST) Daejeon, Republic of Korea
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2021.03.05 View 24655