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'Think Out of the Box,' Team Circos Wins the P4G Innovation Sprint
<The winning team of the P4G Innovation Sprint poses with the Crown Prince of Denmark (sixth from the left in the first row) and President Shin (fifth from the left in the first row) during the awarding ceremony.> Team Circos from KAIST and Denmark made a new sustainable business model for Hempel, a global coating supplier group in Denmark, and won the first prize at the P4G (the Partnership for Green Growth and Global Goals) Innovation Sprint held at KAIST’s Seoul campus on May 22. The six-member team was awarded one million KRW in prize money by the Crown Prince of Denmark. Two of winning team members have the privilege of traveling to visit Hempel in Denmark. The winning team thought outside the box, inspired by box wine which reduced the sales price from traditional bottled wine. Six teams made up of members from different academic disciplines spent two nights and three days brainstorming ways to resolve the challenges of corporations such as Velux and Hempel from Denmark and SK from Korea. The P4G Innovation Sprint is one of the events co-hosted by KAIST and Technological University of Denmark in celebration of the 60th anniversary of diplomatic relations establishment between Denmark and Korea and the 8th anniversary of the Green Growth Alliance between the two countries. The Crown Prince Couple also made a royal visit to Korea in honor of the 60th anniversary celebration and Green Growth Alliance between the two countries. This Innovation Sprint aimed to develop young academics’ perspectives, skills, and talents for the next generation to better research the Sustainable Development Goals set by UN. Three teams made their final five-minute pitches before the Crown Prince and President Sung-Chul Shin and responded to questions from the four-member jury. The Crown Prince of Denmark and President Shin both agreed that the collaborative and convergent ideas will address global problems. The Crown Prince stressed in his congratulatory remarks the importance of partnership in this polarizing world to achieve sustainable improvements saying, “Partnerships are only possible to sustain through collaboration and hard work while staying curious, creative, and critical. " He also shared the special relationship with KAIST. His father-in-law Professor John Donaldson used to be a visiting professor of applied mathmatics at KAIST back in 2003. President Shin added, “Collaboration across boundaries is most critical for responding to these issues. In that sense, this P4G Innovation Sprint is a shining example for demonstrating the collaborative efforts between teammates from diverse disciplines. When we work together and build convergent ideas, we will be more innovative and go further.” <Winning team member Nicolai Thorball from DTU pitches at the final in the presence of the Crown Prince of Denmark and KAIST President Shin.> “The canned packaging in the paint industry results in 40 times more carbon emission in the course of production. However, when using aluminum packaging which is recyclable, the waste amount will be cut dramatically,” pitched Nicolai Thorball from DTU on exchange at Seoul National University. Nicolai, whose major is environmental engineering, is one of two Danish students including Thomsen Xandra Flyvbjerg from the University of Southern Denmark. Flyvbjergy, majoring in business, is now on exchange at Sungkynkwan University. “I am very glad to have the chance to understand the concept of the circular economy and green growth at the sprint. It was also very challenging to make ideation from so many ideas brainstormed,” said Dong-Eun Lee, a KAIST undergraduate from the Department of Biological Sciences. He said that he learned a lot from his two other teammates who are from the Program of Green Business & Policy at KAIST College of Business, Jae-Hee Park and Kyung-Hyun Kim. Juho Park majoring in mechanical engineering at KAIST was one of the team. Circos’ solution for a sustainable model received acclaim from the jury members. DTU Senior Vice President Marianne Thellerson, one of jurors, claimed their model has very high market feasibility, saying, “Their idea could be commercialized right now into the market.” Professor Hee-Kyung Park from KAIST who helped participants’ ideation as one of four mentors said, “The winning team perfectly met all the components of the evaluation criteria, Solution, Acceleration, and Pitch.” At this sprint, 10 students from Denmark and 29 KAIST students were divided into 6 teams and given the challenges of three companies. The Danish window facility company Velux presented its future glass window system and the paint company Hempel their circular economic new business model. SK challenged the students to help it become a global clean energy solution company. The event was based on a hacker blueprint that found the optimal solution to the topics proposed.
2019.05.23
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Professor Yim Appointed As Associate Editor of Nuclear Technology
Professor Man-Sung Yim from the Department of Nuclear and Quantum Engineering was appointed as the associate editor (for the Asian region) of Nuclear Technology ― a leading international research journal of the American Nuclear Society. Professor Yim will serve his term for three years from May 2019. The American Nuclear Society, established in 1954, is comprised of more than 11,000 global members and aims to advance nuclear science, engineering, and technology while supporting the peaceful and beneficial applications of nuclear energy. Since its first publication in 1971, Nuclear Technology has been a representative journal of the society, reporting state-of-the-art information on all phases of the practical applications of nuclear technology. Professor Yim is being recognized worldwide for his pioneering nuclear education, research, and policy studies in the fields of non-proliferation, safeguards for severe accident management, and waste management. He served as the head professor of the Department of Nuclear and Quantum Engineering and established the Nonproliferation Education and Research Center (NEREC) at KAIST. Professor Yim remarked, “Asia has an important role to play at the forefront of the world’s nuclear research considering that nuclear development is most actively being carried out in the Asian region these days.”
2019.05.17
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Engineered Microbial Production of Grape Flavoring
(Image 1: Engineered bacteria that produce grape flavoring.) Researchers report a microbial method for producing an artificial grape flavor. Methyl anthranilate (MANT) is a common grape flavoring and odorant compound currently produced through a petroleum-based process that uses large volumes of toxic acid catalysts. Professor Sang-Yup Lee’s team at the Department of Chemical and Biomolecular Engineering demonstrated production of MANT, a naturally occurring compound, via engineered bacteria. The authors engineered strains of Escherichia coli and Corynebacetrium glutamicum to produce MANT through a plant-based engineered metabolic pathway. The authors tuned the bacterial metabolic pathway by optimizing the levels of AAMT1, the key enzyme in the process. To maximize production of MANT, the authors tested six strategies, including increasing the supply of a precursor compound and enhancing the availability of a co-substrate. The most productive strategy proved to be a two-phase extractive culture, in which MANT was extracted into a solvent. This strategy produced MANT on the scale of 4.47 to 5.74 grams per liter, a significant amount, considering that engineered microbes produce most natural products at a scale of milligrams or micrograms per liter. According to the authors, the results suggest that MANT and other related molecules produced through industrial processes can be produced at scale by engineered microbes in a manner that would allow them to be marketed as natural one, instead of artificial one. This study, featured at the Proceeding of the National Academy of Sciences of the USA on May 13, was supported by the Technology Development Program to Solve Climate Changes on Systems Metabolic Engineering for Biorefineries from the Ministry of Science and ICT. (Image 2. Overview of the strategies applied for the microbial production of grape flavoring.)
2019.05.15
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Autophagy in Dendritic Cells Helps Anticancer Activity
Autophagy contributes to the homeostasis of a cell and recently another function of autophagy has been reported. A KAIST research team found that the autophagy of dendritic cells supports T-cell anticancer activity. Autophagy is a process of maintaining cell homeostasis by removing cellular waste and damaged cellular organelles; nevertheless, its role in the presentation of phagocytized tumor-associated antigens remains vague. Meanwhile, dendritic cells are the ones that recognize pathogens or cancer antigens, and induce immune responses in T cells. When cancer cells are killed by radiation or an anticancer drug, dendritic cells absorb and remove them and present antigens on their surface to transfer them to T-cells. Professor Heung Kyu Lee from the Graduate School of Medical Science and Engineering and his team found that the autophagy of dendritic cells plays a key role in T-cell activation and they proposed the principles of enhancing anti-cancer effects. Their experiments showed that T-cell activation of dendritic cells as well as anticancer immune response dropped when there is a deficiency of Atg5 (autophagy-related) in dendritic cells. Interestingly, Atg5-deficient dendritic cells significantly elevated receptor CD36 on the surface of the cells, which increased the phagocytosis of apoptotic tumor cells yet restricted the activation of T-cells. At this time, when introducing antibodies into the system in order to block the receptor CD36, the anti-tumor T-cell response increased substantially while tumor growth declined. Professor Lee said, “This study allowed us to explore the role of autophagy in the anti-cancer immune response of T-cells. We look forward to developing targeted anti-cancer therapies using the receptor CD36.” This research was published in Autophagy (10.1080/15548627.2019.1596493) on March 22, 2019. Figure 1.Mechanism of autophagy in dendritic cells Figure 2. A role of autophagy in dendritic cells
2019.05.13
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Research Day Highlights Most Outstanding Research Achievements
Professor Byung Jin Cho from the School of Electrical Engineering was selected as the Grand Research Prize Winner in recognition of his innovative research achievement in the fields of nano electric and flexible energy devices during the 2019 KAIST Research Day ceremony held on April 23 at the Chung Kunmo Conference Hall. The ten most outstanding research achievements from the past year were also awarded in the three areas of Research, Innovation, Convergence Researches. Professor Cho is an internationally recognized researcher in the field of future nano and energy device technology. Professor Cho’s team has continued to research on advanced CMOS (complementary metal-oxide semiconductors). CMOS has become his key research topic over the past three decades. In 2014, he developed a glass fabric-based thermoelectric generator, which is extremely light and flexible and produces electricity from the heat of the human body. It is so flexible that the allowable bending radius of the generator is as low as 20 mm. There are no changes in performance even if the generator bends upward and downward for up to 120 cycles. His wearable thermoelectric generator was selected as one of the top ten most promising digital technologies by the Netexplo Forum in 2015. He now is working on high-performance and ultra-flexible CMOS IC for biomedical applications, expanding his scope to thermal haptic technology in VR using graphene-CMOS hybrid integrated circuits; to self-powered wireless sensor nodes and self-powered ECG system using wearable thermoelectric generators . In his special lecture at the ceremony, Professor Cho stressed the importance of collaboration in making scientific research and presented how he moved to future devices after focusing on scaling the devices. “When I started the research on semiconductors, I focused on how to scale the device down as much as possible. For decades, we have conducted a number of procedures to produce tiny but efficient materials. Now we have shifted to develop flexible thermoelements and wearable devices,” said Professor Cho. “We all thought the scaling down is the only way to create value-added technological breakthroughs. Now, the devices have been scaled down to 7nm and will go down to 5 nm soon. Over the past few years, I think we have gone through all the possible technological breakthroughs for reducing the size to 5nm. The semiconductor devices are made of more 1 billion transistors and go through 1,000 technological processes. So, there won’t be any possible way for a single genius to make a huge breakthrough. Without collaboration with others, it is nearly impossible to make any new technological breakthroughs.” Professor Cho has published more than 240 papers in renowned academic journals and presented more than 300 papers at academic conferences. He has also registered approximately 50 patents in the field of semiconductor device technology. The top ten research highlights of 2018 as follows: - Rydberg-Atom Quantum Simulator Development by Professor Jaewook Ahn and Heung-Sun Sim from the Department of Physics - From C-H to C-C Bonds at Room Temperature by Professor Mu-Hyun Baik from the Department of Chemistry - The Role of Rodlike Counterions on the Interactions of DNAs by Professor Yong Woon Kim of the Graduate School of Nanoscience and Technology - The Medal Preoptic Area Induces Hunting-Like Behaviors to Target Objects and Prey by Professor Daesoo Kim from the Department of Biological Sciences - Identification of the Origin of Brain Tumors and New Therapeutic Strategy by Professor Jeong Ho Lee from the Graduate School of Medical Science and Engineering - The Linear Frequency Conversion of Light at a Spatiotemporal Boundary by Professor Bumki Min from the Department of Mechanical Engineering - An Industrial Grade Flexible Transparent Force Touch Sensor by Professor Jun-Bo Yoon from the School of Electrical Engineering - The Detection and Clustering of Mixed-Type Defect Patterns in Wafer Bin Maps by Professor Heeyoung Kim from the Department of Industrial and Systems Engineering - The Development of a Reconfigurable Spin-Based Logic Device by Professor Byong-Guk Park from the Department of Materials Science and Engineering - The Development of a Miniaturized X-Ray Tube Based on Carbon Nanotube and Electronic Brachytherapy Device by Professor Sung Oh Cho from the Department of Nuclear and Quantum Engineering Professor YongKeun Park from the Department of Physics and Professor In-Chel Park from the School of Electrical Engineering received the Research Award. For the Innovation Award, Professor Munchurl Kim from the School of Electrical Engineering was the recipient and the Convergence Research Awards was conferred to Professor Sung-Yool Choi from the School of Electrical Engineering, Professor Sung Gap Im from the Department of Chemical and Biomolecular Engineering, and Professor SangHee Park from the Department of Materials Science and Engineering during the ceremony. For more on KAIST’s Top Research Achievements and Highlight of 2018, please refer to the attached below. click.
2019.04.25
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Professor Ji-Hyun Lee Awarded the Sasada Prize
Professor Ji-Hyun Lee from the Graduate School of Culture Technology was awarded the Sasada Prize during the 24th annual Conference of Computer-Aided Architectural Design Research in Asia (CAADRIA) held in Wellington, New Zealand on April 15. The Sasada Award honors the late Professor Tsuyoshi Sasada (1941-2005), the former Professor of Osaka University and co-founder and fellow of CAADRIA. It is given to an individual who has contributed to the next generation of researchers and academics, to the wider profession and practice in computer-aided design and research, and has earned recognition in the academic community. Professor Lee was recognized for her development of CAAD (Computer-Aided Architectural Design) through her research work on the land price precision system using case-based reasoning. Her research team proposed a model for estimating the average apartment price in an administrative district after collecting 40 variables from the six major Korean cities, excluding Seoul and Ulsan. Their follow-up studies showed the possibility of replacing existing experts’ predictions. Professor Lee has been steadily researching for 20 years on case-based reasoning (CBR), a field of artificial intelligence, and has published more than 40 papers in the field of CBR. Meanwhile, the CAAD Future 2019 event will be held at KAIST in June.
2019.04.23
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Unravelling Inherent Electrocatalysis to Improve the Performance of Hydrogen Fuel Cells
(Figure 1. Electrode structure for the precise evaluation of the metal nanoparticles’ electrochemical catalytic characteristics at a high temperature.) A KAIST team presented an ideal electrode design to enhance the performance of high-temperature fuel cells. The new analytical platform with advanced nanoscale patterning method quantitatively revealed the electrochemical value of metal nanoparticles dispersed on the oxide electrode, thus leading to electrode design directions that can be used in a variety of eco-friendly energy technologies. The team, working under Professor WooChul Jung and Professor Sang Ouk Kim at the Department of Materials Science and Engineering, described an accurate analysis of the reactivity of oxide electrodes boosted by metal nanoparticles, where all particles participate in the reaction. They identified how the metal catalysts activate hydrogen electro-oxidation on the ceria-based electrode surface and quantify how rapidly the reaction rate increases with the proper choice of metals. Metal nanoparticles with diameters of 10 nanometers or less have become a key component in high-performance heterogeneous catalysts, primarily serving as a catalytic activator. Recent experimental and theoretical findings suggest that the optimization of the chemical nature at the metal and support interfaces is essential for performance improvement. However, the high cost associated with cell fabrication and operation as well as poorer stability of metal nanoparticles at high temperatures have been a long-standing challenge. To solve this problem, the team utilized a globally recognized metal nano patterning technology that uses block copolymer self-assembled nano templates and succeeded in uniformly synthesizing metal particles 10 nanometers in size on the surface of oxide fuel cell electrodes. They also developed a technology to accurately analyze the catalyst characteristics of single particles at high temperatures and maximize the performance of a fuel cell with minimal catalyst use. The research team confirmed that platinum, which is a commonly used metal catalyst, could boost fuel cell performance by as much as 21 times even at an amount of 300 nanograms, which only costs about 0.015 KRW. The team quantitatively identified and compared the characteristics of widely used metal catalysts other than platinum, such as palladium, gold, and cobalt, and also elucidated the precise principle of catalyst performance through theoretical analysis. (Figure 2. Comparison of the electrochemical catalytic characteristics for various 10nm metal nanoparticles (platinum, palladium, cobalt, gold) at a high temperature.) Professor Jung said, "We have broken the conventional methods of increasing the amount of catalyst which have deemed inefficient and expensive. Our results suggest a clear idea for high performance fuel cells using very small amounts of nanoparticles. This technology can be applied to many different industrial fields, advancing the commercialization of eco-friendly energy technologies such as fuel cells that generate electricity and electrolytic cells that produce hydrogen from water.” The research has been published as the cover article of Nature Nanotechnology in the March issue. This research was carried out with support from the Nano-Material Technology Development Program through the National Research Foundation of Korea.
2019.03.28
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Distinguished Professor Sang Yup Lee Honored with the 23rd NAEK Award
(Distinguished Professor Sang Yup Lee from the Department of Chemical and Biomolecular Engineering) Distinguished Professor Sang Yup Lee from the Department of Chemical and Biomolecular Engineering was honored to be the laureate of the 23rd NAEK Award. The NAEK (National Academy of Engineering of Korea) Award was instituted in 1997 to honor and recognize engineers who have made significant contributions to the development of the engineering and technology field at universities, industries, and institutions. Every year, it is conferred to only one person who has achieved original and world-leading research that has led to national development. Distinguished Professor Lee is a pioneering scholar of the field of systems metabolic engineering and he was recognized for his significant achievements in the biochemical industry by developing novel microbial bioprocesses. In particular, he is globally renowned for biological plastic synthesis, making or decomposing polymers with microorganisms instead of using fossil resources. He has produced numerous high-quality research breakthroughs in metabolic and systems engineering. In 2016, he produced an easily degradable plastic with Escherichia coli (E. coli). In 2018, he successfully produced aromatic polyesters, the main material for PET (poly ethylene terephthalate) from E. coli strains. He also identified microorganism structures for PET degradation and improved its degradability with a novel variant. His research was ranked number one in the research and development division of Top Ten Science and Technology News 2018 announced by Korean Federation of Science & Technology Societies. He is one of highly cited researchers (HCR) ranked in the top 1% by citations for their field by the Clarivate Analytics.
2019.03.21
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The Future Mobility of the Year 2019
KAIST announced the Future Mobility of the Year (FMOTY) 2019. The winners are Volvo 360C, Toyota e-Palette, and Toyota Concept-i WALK. FMOTY are the first awards that recognizes concept cars that exhibit innovative services and practical transportation technology in three categories: private mobility, public and commercial mobility, and personal mobility. Figure 1. The winner in the private mobility division, the Volvo 360C In the private mobility division, the award went to the Volvo 360C. With targeted routes of roughly 186 miles, this vehicle has an ambitious service goal to replace airplanes by traveling these routes with great comfort. Goro Okazaki, a journalist with Car and Driver Japan, said, “The Volvo 360C clearly shows how highly personalized autonomous driving can change the future.” Figure 2. The winner in the public mobility division, the Toyota e-Palette The Toyota e-Palette was the winning car in commercial mobility division. This vehicle provides the best solution as a mobile service platform by transforming itself into mobile hospitals, hotels, stores and food trucks. Carlo Calderón, a journalist for Autopista Spain, said, “It has a great strength in remodeling its indoor and outdoor spaces according to various commercial uses.” Figure 3. The winner in the personal mobility division, the Toyota Concept-i WALK In the personal mobility division, the award went to the Toyota Concept-i WALK. It was recognized for having an exquisite user environment and artificial intelligent agent, along with an excellent completion. Jun Miao, a journalist with MJ CarShow China, said, “It is aesthetically pleasing. Beyond the upright control of conventional personal mobility, it allows agile control with a joystick.” FMOTY conducted a screening process for 45 concept cars over three months and 16 renowned automotive experts from 11 countries participated as judges for this award, including Editor in Chief of BBC Top Gear Magazine Charlie Turner and European Bureau Chief of Automobile Magazine Georg Kacher. The judges said that FMOTY was born to propose a new aspect of future mobility, and in terms of evaluating technical and social values of concept cars, FMOTY carries great significance. Kyung-soo Kim, Dean of the Cho Chun Shik Graduate School of Green Transportation said, “Globally renowned experts in the automotive field participated as judges to elevate the prestige and fairness of the awards. KAIST members were excluded from the entire judging process. I believe that the FMOTY Awards will expand public attention from the present to the future.” Details can be found on the official website of FMOTY ( www.fmoty.org ).
2019.03.11
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KAIST Develops Analog Memristive Synapses for Neuromorphic Chips
(Professor Sung-Yool Choi from the School of Electrical Engineering) A KAIST research team developed a technology that makes a transition of the operation mode of flexible memristors to synaptic analog switching by reducing the size of the formed filament. Through this technology, memristors can extend their role to memristive synapses for neuromorphic chips, which will lead to developing soft neuromorphic intelligent systems. Brain-inspired neuromorphic chips have been gaining a great deal of attention for reducing the power consumption and integrating data processing, compared to conventional semiconductor chips. Similarly, memristors are known to be the most suitable candidate for making a crossbar array which is the most efficient architecture for realizing hardware-based artificial neural network (ANN) inside a neuromorphic chip. A hardware-based ANN consists of a neuron circuit and synapse elements, the connecting pieces. In the neuromorphic system, the synaptic weight, which represents the connection strength between neurons, should be stored and updated as the type of analog data at each synapse. However, most memristors have digital characteristics suitable for nonvolatile memory. These characteristics put a limitation on the analog operation of the memristors, which makes it difficult to apply them to synaptic devices. Professor Sung-Yool Choi from the School of Electrical Engineering and his team fabricated a flexible polymer memristor on a plastic substrate, and found that changing the size of the conductive metal filaments formed inside the device on the scale of metal atoms can make a transition of the memristor behavior from digital to analog. Using this phenomenon, the team developed flexible memristor-based electronic synapses, which can continuously and linearly update synaptic weight, and operate under mechanical deformations such as bending. The team confirmed that the ANN based on these memristor synapses can effectively classify person’s facial images even when they were damaged. This research demonstrated the possibility of a neuromorphic chip that can efficiently recognize faces, numbers, and objects. Professor Choi said, “We found the principles underlying the transition from digital to analog operation of the memristors. I believe that this research paves the way for applying various memristors to either digital memory or electronic synapses, and will accelerate the development of a high-performing neuromorphic chip.” In a joint research project with Professor Sung Gap Im (KAIST) and Professor V. P. Dravid (Northwestern University), this study was led by Dr. Byung Chul Jang (Samsung Electronics), Dr. Sungkyu Kim (Northwestern University) and Dr. Sang Yoon Yang (KAIST), and was published online in Nano Letters (10.1021/acs.nanolett.8b04023) on January 4, 2019. Figure 1. a) Schematic illustration of a flexible pV3D3 memristor-based electronic synapse array. b) Cross-sectional TEM image of the flexible pV3D3 memristor
2019.02.28
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Stretchable Multi-functional Fiber for Energy Harvesting and Strain Sensing
(from left: Professor Steve Park, Jeongjae Ryu and Professor Seungbum Hong) Fiber-based electronics are expected to play a vital role in next-generation wearable electronics. Woven into textiles, they can provide higher durability, comfort, and integrated multi-functionality. A KAIST team has developed a stretchable multi-functional fiber (SMF) that can harvest energy and detect strain, which can be applied to future wearable electronics. With wearable electronics, health and physical conditions can be assessed by analyzing biological signals from the human body, such as pulse and muscle movements. Fibers are highly suitable for future wearable electronics because they can be easily integrated into textiles, which are designed to be conformable to curvilinear surfaces and comfortable to wear. Moreover, their weave structures offer support that makes them resistant to fatigue. Many research groups have developed fiber-based strain sensors to sense external biological signals. However, their sensitivities were relatively low. The applicability of wearable devices is currently limited by their power source, as the size, weight, and lifetime of the battery lessens their versatility. Harvesting mechanical energy from the human body is a promising solution to overcome such limitations by utilizing various types of motions like bending, stretching, and pressing. However, previously reported, fiber-based energy harvesters were not stretchable and could not fully harvest the available mechanical energy. Professor Seungbum Hong and Professor Steve Park from the Department of Materials Science and Engineering and their team fabricated a stretchable fiber by using a ferroelectric layer composed of P(VDF-TrFE)/PDMS sandwiched between stretchable electrodes composed of a composite of multi-walled carbon nanotubes (MWCNT) and poly 3,4-ethylenedioxythiophene polystyrenesulfonate (PEDOT:PSS). Cracks formed in MWCNT/PEDOT:PSS layer help the fiber show high sensitivity compared to the previously reported fiber strain sensors. Furthermore, the new fiber can harvest mechanical energy under various mechanical stimuli such as stretching, tapping, and injecting water into the fiber using the piezoelectric effect of the P(VDF-TrFE)/PDMS layer. Professor Hong said, “This new fiber has various functionalities and makes the device simple and compact. It is a core technology for developing wearable devices with energy harvesting and strain sensing capabilities.” This article, led by PhD candidate Jeongjae Ryu, was published in the January 2019 issue of Nano Energy. Figure 1.Schematic illustration of an SMF fiber and its piezoelectric voltage output and response to strain. Figure 2. Photographs of a stretchable multi-functional fiber being stretched by 100%, bent, and twisted.
2019.01.31
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Hierarchical Porous Titanium Nitride Synthesized by Multiscale Phase Separation for LSBs
(from left: Professor Jinwoo Lee and PhD candidate Won-Gwang Lim) A KAIST research team developed ultra-stable, high-rate lithium-sulfur batteries (LSBs) by using hierarchical porous titanium nitride as a sulfur host, and achieved superior cycle stability and high rate performance for LSBs. The control of large amounts of energy is required for use in an electric vehicle or smart grid system. In this sense, the development of next-generation secondary batteries is in high demand. Theoretically, LSBs have an energy density seven times higher than commercial lithium ion batteries (LIBs). Also, their production cost can be reduced dramatically since sulfur can be obtained at a low price. Despite these positive aspects, there have been several issues impeding the commercialization of LSBs, such as the low electric conductivity of sulfur, the dissolution of active materials during operation, and sluggish conversion reactions. These issues decrease the cycle stability and rate capability of batteries. To tackle those issues, Professor Jinwoo Lee from the Department of Chemical and Biomolecular Engineering and his team synthesized a well-developed hierarchical macro/mesoporous titanium nitride as a host material for sulfur. The titanium nitride has a high chemical affinity for sulfur and high electrical conductivity. As a result, it prevents the dissolution of active materials and facilitates the charge transfer. Moreover, the synergistic effect of macropore and mesopore structures allows the stable accommodation of large amounts of sulfur and facilitates the electrolyte penetration. Previously reported polar inorganic materials have a high affinity for sulfur, but it was challenging to control the porous architecture suitable to the sulfur host. This work breaks such limitations by developing a synthetic route to easily control the porous architecture of inorganic materials, which led to obtaining superior cycle stability and high rate capabilities. Professor Lee said, “Some problems still remain in commercializing LSBs as next-generation batteries. Hence, there should be a continued research on this matter to solve the issues. Through this research, we secured a key technology for ultrastable, high-rate LSBs.” This research was led by PhD candidate Won-Gwang Lim and collaborated on by Jeong Woo Han from POSTECH. It was chosen as the cover article of Advanced Materials on January 15, 2019. Figure 1. Schematic illustration for the synthetic route of co-continuous h-TiN Figure 2. The hierarchical multiscale porous structure is still retained without any collapse after the conversion to h-TiN. The good retention of the porous structure is attributed to the thick pore wall of the h-TiO₂derived from the block copolymer self-assembly Figure 3. The cover page of Advanced Materials
2019.01.28
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